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Flash Vacuum Pyrolysis of o-Xylylene Dimers

Flash vacuum pyrolysis of [4+4] dimers of o-xylylenes gives anthracenes as the major products, and this remarkable transformation is highly regiospecific. Thus, the methyl-substituted derivative 1 gives 2 while 3 gives 4. [Pg.54]

Elucidate the overall synthesis and give a mechanism for the final step. [Pg.54]


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Flash of

Flash pyrolysis

Flash vacuum pyrolysi

Flash vacuum pyrolysis

O dimerization

O-Xylylene

O-Xylylenes

O-Xylylenes dimerization

Pyrolysis vacuum

Vacuum flashing

Xylylene

Xylylenes

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