Flash Photolysis Studies in Bimolecular Electron-transfer Processes

2 Flash Photolysis Studies in Bimolecular Electron-transfer Processes [Pg.187]

By using pulsed laser sources and fast measuring devices, direct observation of redox products in flash photolysis experiments provides evidence regarding oxidative and reductive quenching mechanisms in Ru(bpy)3+. [Pg.187]

Order Reaction and Rate Law Integrated Rate Law Plot [Pg.188]

Determination of changes in the absorbance (AA) of a solution of the complex containing a quencher can be investigated when a pulse of laser light excites Ru(bpy)j+. The principal spectral characteristics of the complex and its derived transient species are given in Table 10.3. [Pg.188]

These features are consistent with the reductive quenching mechanism of Ru(bpy)3+ [Pg.188]

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