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Ferrocene-rhenium complexes

These ketophosphine complexes all exhibit reversible one-electron oxidation of the ferrocene fragment. In addition, as shown in Fig. 7-21, [(> -C5H5)Fe (> -C5H4C(0)CHPPh2)Re(C0)3Br ][NMe4] also displays a subsequent two-electron oxidation. Access to such a rhenium-centered process is likely to be electrostatically favored because of the anionic nature of the complex [77]. [Pg.342]

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Rhenium complexes

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