Ferf-Butyl perbenzoate, reaction with

C. Electron Transfer Reactions (ETR) of ferf-Butyl Perbenzoates with Dimethyl Sulfide ... 

Absolute and relative rates of ETR of ferf-butyl perbenzoates with dimethyl sulfide at various temperatures (T = 80, 90, 100 and 110°C) were obtained. Hammett correlations at each temperature were also studied (Table 7). The Hammett slopes are positive and the reactions are better correlated with a rather than with a 1. This indicates that a negative charge resides on the benzoyloxy group without conjugation with the phenyl... 

The synthesis of ferf-butyl ethers by the reaction of Grignard reagents with tert-butyl perbenzoate appears to have considerable... 

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