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Fedors supposition

Askadskii has shown that Fedors supposition eoneeming the additivity of eontributions of volume of atoms or groups of atoms is not quite eorreet beeause the same atom in an environment of different atoms oeeupies different volume. In addition, atoms ean internet with other atoms in different ways depending on their disposition and this should be taken into aeeount for eomputation of eohesion energy. Therefore, anew seheme of the solubility parameters ealeulation was proposed that takes into aeeount the nature of an environment of eaeh atom in a moleeule and the type of intermoleeular interaetions. This approaeh is similar to that deseribed in the work of Rheineek and Lin. ... [Pg.263]


See also in sourсe #XX -- [ Pg.289 ]




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