Fe-M heterometallics

The spin state of FeCr(N(o-(NCH2P Pr2)CgH4)3) was determined to be 5 = V2 based on an axirJ EPR signrJ that was modeled with = (1.944,1.935, and 1.759). The low -values = 1.88) are consistent 

Iron-cobalt bonds have also been studied within Fe-Co heterotrimetallics featuring FejCo and FeCOj cores [225]. The mixed-metal clusters were synthesized using a novel strategy of metal atom substitution (Co) into a preexisting Fej core, [(L )Fe3(p-Cl)]2. The addition of 2 and Sequiv. of 

Fe-Group 10 Heterometallics The triad of Group 10 metals readily forms bonds with iron in a class of bimetallic complexes with related chemical formulas, (OC)3Fe(p-dppm)(p-L)MX, as shown 

Fe-Group 11 Heterometallics The Fe(CO)2Cp fragment, which was described earlier as a het-erometallic partner with electrophilic Group 4 metals, also forms unsupported metal-mettd bonds with Cu. The FeCu+ complexes are formed in salt elimination reactions between various NHC-ligated 

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