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Facile intramolecular site exchange

Soon after the discovery of H2 complexes facile intramolecular site exchange of H atoms between H2 and hydride ligands was found to occur [61]. The NMR signals of the cis H2 and hydride in [Ir(H2)H(bq)(PPh3)2]+ coalesce at 240 K because of exchange, and even the hydride trans to H2 in [Fe(H2)H(dppe)2]+ exchanges positions with the H atoms of... [Pg.623]

See other pages where Facile intramolecular site exchange is mentioned: [Pg.606]    [Pg.362]    [Pg.200]    [Pg.14]    [Pg.624]    [Pg.353]    [Pg.347]    [Pg.383]    [Pg.499]    [Pg.125]    [Pg.156]    [Pg.1029]   
See also in sourсe #XX -- [ Pg.623 ]



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Intramolecular exchange

Intramolecular site exchanges

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