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Exponential unitary transformations of states in Fock space

3 EXPONENTIAL UNITARY TRANSFORMATIONS OF STATES IN FOCK SPACE [Pg.89]

The usefulness of the exponential operator exp(—ic) becomes clear when we consider the transformed ON vector (3.2.12). Inserting the expression for the transformed creation operators (3.2.3) into (3.2.12), we obtain [Pg.89]

A similar expression must hold for any linear combination of ON vectors - that is, for any state in Fock space. We have thus established equation (3.2.5) applied to any electronic state 0), the operator exp(— ) generates a new state 0) where all the spin orbitals have been unitarily transformed according to (3.2.1). [Pg.89]




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Exponential transformations

Fock space

In Fock space

In transformations

Space of states

Space transformations

Space unitary

State space transformation

State-space

Transformation unitary

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