Experimental laser diffraction technique

The former approach, attempting to measure the droplets in their fully hydrated state, has enjoyed more widespread use. Experimentally, this has been accomplished in a number of ways. The use of low-flow impactors that entrain minimal quantities of ambient air and hence maintain the quasiequilibrium humidity exiting the nebulizer is one approach (30). Adding humidified dilution air, rather than ambient air, to a high-volume cascade impactor is another. Cooling the impactor to the same temperature as the nebulizer cloud (reservoir) has also been shown to be an effective way of providing sufficient stabilization for aerosol measurement purposes (31). However, a technique that has been used extensively in conjunction with a large number of deposition studies is laser diffraction (3). As described above, this technique measures the physical diameter... 

Experimentally, this technique is very similar to the TDI technique described above. A laser beam is incident normally on a diffraction grating or a preferentially scratched mirror deposited on the surface to obtain the normally reflected beam and the diffracted beams as described above. Instead of recombining the two beams that are located symmetrically from the normally reflected beam, each individual beam at an angle d is monitored by a VISAR. Fringes Fg produced in the interferometers are proportional to a linear combination of both the longitudinal U(t) and shear components F(t) of the free surface velocity (Chhabildas et al., 1979), and are given by... 

Although several metal-containing heterocyclic compounds (such as porphyrins, phthalocyanines, naphthenates) are present in oil fractions most of the bench-scale research has been based on relatively rapid Ni, V, or Ni/V deposition procedures in which experimental FCC formulations have been artificially metal contaminated with solutions of Ni and/or V naphthenate dissolved in benzene (or toluene) (24). Metal levels in these novel FCC are usually above 0.5% that is well above the concentration that today exist on equilibrium FCC, see Figure 1. High metal concentration facilitate the study and characterization of Ni and V effects by modern characterization techniques such as X-ray photoelectron spectroscopy (XPS), Laser Raman spectroscopy (LRS), X-ray diffraction (XRD), electron microscopy, secondary ion mass spectrometry (SIMS), and 51V nuclear magnetic resonance (NMR). 

A significant role in future research will be played by molecular dynamics simulation as well as other new and very promising computational techniques, made possible by the advent of supercomputers. Also of importance are new and more sophisticated experimental techniques, such as NMR, laser correlation spectroscopy, neutron diffraction, and laser fluorescence bleaching recovery. These new techniques will surely yield new insights into the mechanisms of transport of small molecules in both rubbery and glassy polymers. 

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