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Exchange field interaction between

The dispersive and exchange-repulsive interactions between atoms and molecules can be calculated using quantum mechanics, though such calculations are far from trivial, requiring electron correlation and large basis sets. For a force field we require a means to model the interatomic potential curve accurately (Figure 4.32), using a simple empirical... [Pg.206]

The study of exchange interactions between transition-metal ions and copper(II) in particular has been an active field of research (Section 6.6.3.6).254-256 In this context, Verdaguer and co-workers investigated complexes (292) and (293), supported by flexible 2,2 -bipyrimidine.257... [Pg.796]

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