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Ethylene complex with BrCl

Reaction of alkenes with BrCl proceeds via the intermediate [alkene-Br]+ rather than the intermediate [alkene-Cl]+. Explain using a two-orbital interaction diagram. (The structure of the complex between ethylene and BrCl in the gas phase has been determined by microwave spectroscopy. It is T-shaped, with the BrCl molecule lying perpendicular to the ethylene plane and pointing bromine-end first toward the midpoint of the C=C bond Legon, A. C. Bloemink, H. I. Hinds, K. Thorn, J. C., Chem. Eng. News, 1994 Nov. 7, 26-29.)... [Pg.262]


See also in sourсe #XX -- [ Pg.262 ]

See also in sourсe #XX -- [ Pg.262 ]

See also in sourсe #XX -- [ Pg.262 ]

See also in sourсe #XX -- [ Pg.262 ]




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BrCl

Ethylene complexes

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