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Ethyl trifluorothiolacetate, hydrolysis

Of particular interest is the observation of Bender and Heck37 who find from I80 exchange that the value of kjkh (the ratio of the rate coefficients for, sO exchange and for hydrolysis) is in agreement with the value of k 2/k3 from the data of Fedor and Bruice38 on the hydrolysis of ethyl trifluorothiolacetate. The mechanism for this reaction is... [Pg.216]

Solvent D2O kinetic isotopic effect kn/ko > 2 for general base, 0.8-1.9 for nucleophilic catalysis (usually) W D = 3,1 for imidazole-catalyzed hydrolysis of ethyl trifluorothiolacetate 90... [Pg.144]

Fig. 3. pH-rate profile for the hydrolysis of ethyl trifluorothiolacetate in water at 30° and ionic strength = 2 m. From Fedor and Bruice (1965). Reproduced with permission of the American Chemical Society. [Pg.254]

See other pages where Ethyl trifluorothiolacetate, hydrolysis is mentioned: [Pg.300]    [Pg.301]    [Pg.316]    [Pg.300]    [Pg.301]    [Pg.316]    [Pg.145]    [Pg.317]    [Pg.290]   
See also in sourсe #XX -- [ Pg.145 , Pg.216 , Pg.222 ]



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Ethyl hydrolysis

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