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2- Ethyl-1-butene

The reaction of ethylene at -20°C and 1 atm with the phosphine-free catalyst prepared from 77-allylnickel chloride and ethylaluminum dichloride in chlorobenzene results in the rapid formation of a mixture of ethylene dimers with lesser amounts of higher oligomers. The dimer fraction consists mainly of 2-butenes and the trimer fraction of 3-methylpentenes and 2-ethyl-1-butene as well as a minor amount of hexene (97). From the composition of the products it can be concluded that the displacement reaction predominates over the insertion reaction when using the phosphine-free catalyst and that the direction of addition of both the H—Ni and C2H5—Ni species is mainly of the Ni — C2 type. [Pg.121]

DIMETHYL-l-BUTENE 2-ETHYL-1-BUTENE trans-3-METHYL-2-PENTENE... [Pg.13]

ETHYL-1-BUTENE 30.7807 -2.4852E+03 -8.5324E+00 3.0560E-03 1.6108E-14 142 512... [Pg.39]

Ethyl-1-butene-1-one, see Diethylketene, 2424 Ethyl carbamate, 1257 Ethyl carbamimoniothioate... [Pg.2091]

In a similar way, methylene moieties can be achieved by employing siliconeo-pentylmagnesium chloride (287) to carry out a methylenation 190. If 3-pentanone (257) is treated with 287,2-ethyl-1-butene (288) is formed (Scheme 39). For further applications of the Peterson reaction and its modification, see also64,191,192. ... [Pg.59]

Use the formula prefix + root + suffix to put the name together. The full name of this compound is 2-ethyl-1-butene. Remember that a hyphen is placed between numbers and letters, and commas are placed between consecutive numbers. [Pg.556]

Ans. Two more isomers. Less of 2-ethyl-1-butene due to steric constraints at the Rh center. [Pg.166]

The IR spectra of both products show the characteristic absorptions of alkenes in the regions 3020-3100 cm-1 and 1650 cm-1. However, in the region 700-1000 cm-1, 2-ethyl-1-butene shows a strong absorption at 890 cm-1 that is typical of 2,2-disubstituted R2C=CH2 alkenes. The presence or absence of this peak should help to identify the product. (3-Methyl-2-pentene is the major product of the dehydrobromination reaction.)... [Pg.284]

Ethyl-1-butene Methyltrioxorhenium H202/t - BuOH 76% 3-Pentanone 24% 2-Ethyl-1,2-butanediol... [Pg.59]


See other pages where 2- Ethyl-1-butene is mentioned: [Pg.824]    [Pg.826]    [Pg.372]    [Pg.211]    [Pg.77]    [Pg.940]    [Pg.215]    [Pg.557]    [Pg.674]    [Pg.824]    [Pg.864]    [Pg.730]    [Pg.66]    [Pg.94]    [Pg.121]    [Pg.159]    [Pg.185]    [Pg.227]    [Pg.1698]    [Pg.549]    [Pg.240]    [Pg.580]    [Pg.104]    [Pg.104]    [Pg.105]    [Pg.105]    [Pg.388]    [Pg.161]    [Pg.34]    [Pg.81]    [Pg.243]    [Pg.556]    [Pg.536]    [Pg.612]    [Pg.481]    [Pg.596]    [Pg.25]    [Pg.42]    [Pg.127]   
See also in sourсe #XX -- [ Pg.2 , Pg.4 ]




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2- Ethyl-3-methyl-l-butene

2-Ethyl-4- buten

2-Ethyl-4- buten

2-Ethyl-l-butene

4-Butenal, 2-butyl-2-ethyl

Methyl ethyl ketone from -butenes

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