Ethyl amidophosphate

Diethyl monochlorophosphate is a colorless liquid of irritating, unpleasant odor, with boiling point 89° (at 15 mm.), n 5, 1.4150. It fumes in moist air and reacts vigorously with water. It reacts with ammonia to give ethyl-amidophosphate and with amines to give substituted ethylamidophosphates.5... 

Reactions of phosphites at centres other than carbon have also been reported. Treatment of the azide (123) with triethyl phosphite in toluene initially yields the Staudinger product (124), which undergoes an unexpected ethyl migration to form the amidophosphate (125). This reaction can be... 

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