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Ethers, tribenzylsilyl prostaglandin epoxidation

To control the stereochemistry of epoxidation at the 10,11-double bond in intermediates in prostaglandin synthesis, a bulky protective group was used for the C15-OH group. Epoxidation of the tribenzylsilyl ether yielded 88% a-oxide epoxidation of the tri-/ -xylylsilyl ether was less selective. ... [Pg.84]

See also in sourсe #XX -- [ Pg.657 ]

See also in sourсe #XX -- [ Pg.657 ]



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Prostaglandins epoxidation

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