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Ethers, protonated bidentate complexes

Secondary Oxonium Ions [RR OH ]. 1H NMR and IR investigation75 of protonated ether salts (hexachloroantimonates) in dichloromethane solutions showed the formation of both (a) dialkyloxonium ions in which the proton is bound to only one oxygen (21) and (b) bidentate complexes in which the proton is shared between two ether molecules (22). Structural analysis of such a bidentate complex of diethyl ether with a complex anion shows a broad H+ resonance at 81 H 16.3 and unequal O—H bond distances (1.39 and 1.11 A).76... [Pg.319]

See other pages where Ethers, protonated bidentate complexes is mentioned: [Pg.10]    [Pg.244]    [Pg.131]    [Pg.1200]    [Pg.80]    [Pg.53]    [Pg.1970]    [Pg.3039]    [Pg.83]    [Pg.255]   
See also in sourсe #XX -- [ Pg.319 ]



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Bidentates

Complex bidentate

Ether complexes

Ethere protonated

Ethers protonation

Proton complexes

Protonated complex

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