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1.2- Ethanediamine metal complexes

Kx for copper (II)-diamine complex is 10.36 and 9.45 for 1,2-ethanediamine and 1,3-propanediamine, respectively (-2)]. The large difference in the stabilities of the two copper (II)-diamine complexes is attributed to an unfavorable entropy effect associated with an increase in the size of the metal-chelate ring (2). Extrapolating to the / -ketoimine derivatives, it seems reasonable to expect that the stability of bisacetylacetonetrimethylenediiminocopper(II) would be less than that of the ethylenediamine analog and to suspect that the former compound is less stable than bis-(4-iminopentane-2-ono) copper (II). That this is reasonable is... [Pg.201]

See other pages where 1.2- Ethanediamine metal complexes is mentioned: [Pg.1079]    [Pg.1725]    [Pg.1079]    [Pg.1725]    [Pg.127]    [Pg.127]    [Pg.127]    [Pg.127]    [Pg.127]    [Pg.127]    [Pg.411]    [Pg.807]    [Pg.1079]    [Pg.1079]    [Pg.1079]    [Pg.1079]    [Pg.1079]    [Pg.1079]    [Pg.243]    [Pg.373]    [Pg.207]    [Pg.229]    [Pg.263]    [Pg.341]    [Pg.1453]    [Pg.1725]    [Pg.1725]    [Pg.1725]    [Pg.1725]    [Pg.1725]    [Pg.487]    [Pg.373]    [Pg.229]    [Pg.387]    [Pg.263]    [Pg.411]    [Pg.387]    [Pg.1179]    [Pg.115]    [Pg.182]    [Pg.902]    [Pg.908]    [Pg.5194]    [Pg.254]   


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1,2-Ethanediamine complexes

1.2- Ethanediamine

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