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Esters with zinc permanganate

The popularity of the Nef reaction is due in part to the ready availability of nitro compounds. Primary and secondary halides react with sodium nitrite in dimeAyl sulfoxide (DMSO) or dimethylform-amide (DMF) to give useful yields of nitro compounds. Primary amines can be oxidized to nitro compounds with potassium permanganate, m-chloroperbenzoic acitP or ozone. Chlorination of oximes with hypochlorous acid and reduction with magnesium, zinc or hydrogen/lpalladium gives secondary nitro compounds. Stabilized carbanions can be nitrated by treauitent with a nitrate ester, and enol acetates are nitrated by acetyl nitrate to give nitro ketones. ... [Pg.218]

See other pages where Esters with zinc permanganate is mentioned: [Pg.68]    [Pg.68]    [Pg.236]    [Pg.172]    [Pg.236]    [Pg.68]    [Pg.172]    [Pg.218]    [Pg.236]    [Pg.130]    [Pg.694]    [Pg.73]    [Pg.615]    [Pg.764]    [Pg.977]    [Pg.34]    [Pg.565]    [Pg.730]    [Pg.1114]    [Pg.216]    [Pg.341]   
See also in sourсe #XX -- [ Pg.169 ]



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With permanganate

With zinc

Zinc permanganate

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