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Esters Reformatsky reaction, cerium metal

Cerium enolates may also be generated reductively in THF from oi-iodo or a-bromo esters in the presence of an aldehyde or ketone using cerium metal turnings and catalytic HgCk (or cerium amal-gam). This leads to a Reformatsky-type reaction (Volume 2, Chapter 1.7) producing the (3-hydroxy ester (47) as a mixture of diastereomers (equation 16). [Pg.312]

See other pages where Esters Reformatsky reaction, cerium metal is mentioned: [Pg.374]

See also in sourсe #XX -- [ Pg.2 , Pg.312 ]

See also in sourсe #XX -- [ Pg.312 ]

See also in sourсe #XX -- [ Pg.312 ]

See also in sourсe #XX -- [ Pg.2 , Pg.312 ]

See also in sourсe #XX -- [ Pg.312 ]

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Cerium , reaction

Cerium metal

Esters metalation

Reformatski reaction

Reformatsky

Reformatsky reaction

Reformatsky reaction metals