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Esterification of dicarboxylic acids

Phenolic esters are obtained similarly. The presence of a nitro group in the aromatic nucleus and the use of pyridine as solvent facilitates the reaction. This reaction is recommended for the characterization of phenols. 2,4,5-Trichlorophenyl-, pentachlorophenyl-, 4-nitrophenyl- and thiophenyl esters of N-acylamino acids are prepared in this manner. These aromatic esters are used in the stepwise lengthening of peptides, du Vigneaud and coworkers synthesized lysine vasopressin from a nonapeptide which they prepared stepwise using the nitrophenyl ester method. Room temperature esterification of dicarboxylic acids and diphenols are also carbodiimide mediated using the 1 1 complex derived from DMAP and p-toluenesulfonic acid as catalyst Methacrylic acid is also esterified with phenols using carbodiimides and DMPA to mediate the reaction. ... [Pg.114]

Monobifunctional crossUnkers, synthesized in the carbodiimide mediated esterification of dicarboxylic acids in the presence of sodium N-hydroxysuccinimide-3-sulfonate, are used in the mapping of protein structures. " ... [Pg.267]

Literature survey on esterification of dicarboxylic acids with alcohols 24... [Pg.9]


See other pages where Esterification of dicarboxylic acids is mentioned: [Pg.502]    [Pg.22]   
See also in sourсe #XX -- [ Pg.697 , Pg.701 , Pg.703 ]

See also in sourсe #XX -- [ Pg.697 , Pg.701 , Pg.703 ]

See also in sourсe #XX -- [ Pg.607 ]

See also in sourсe #XX -- [ Pg.607 ]




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