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Eremophilane-type sesquiterpene

Kingston DGI, Rao MM, Spittler TD, Isolation and structure determination of fluorensic acid, a new sesquiterpene of the eremophilane type. Tetrahedron Lett... [Pg.467]

Biogenetic schemes have been postulated to account for those sesquiterpenes which can be formally related to a eudesmane-type precursor via a 1,2-methyl migration (see Scheme 4). Thus, the skeletal and stereochemical features exhibited by the eremophilane-type (281) sesquiterpenes can be rationalised in terms of a precursor such as the cation (278), derivable from (277). By similar reasoning. [Pg.100]

The origin of eremophilane sesquiterpenes by migration of a methyl group from C-10 to C-5 in an eudesmane intermediate has been postulated to reconcile the apparent deviation of eremophilanes from the isoprene rule (Cane, 1990). (— )-Aristolochene (12), an eremophilane-type sesquiter-... [Pg.371]

See other pages where Eremophilane-type sesquiterpene is mentioned: [Pg.158]    [Pg.57]    [Pg.639]    [Pg.158]    [Pg.57]    [Pg.639]    [Pg.641]    [Pg.641]    [Pg.925]    [Pg.393]    [Pg.55]    [Pg.143]    [Pg.129]    [Pg.374]    [Pg.99]   
See also in sourсe #XX -- [ Pg.639 ]

See also in sourсe #XX -- [ Pg.18 , Pg.639 ]



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Eremophilane

Eremophilane sesquiterpenes

Eremophilane-type sesquiterpen

Eremophilane-type sesquiterpen

Eremophilanes

Sesquiterpene

Sesquiterpenes

Sesquiterpens

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