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Equilibrium free energy change and

Calculated from the equilibrium free energy change and the calculated free energy of activation for the forward reaction. [Pg.213]

As applied to proton transfers, the theory takes the form of equations 1.7 and 1.8, where kdiff is the diffusion-controlled encounter rate. AG is the free energy of activation defined by equation 1.8, AG° being the standard equilibrium free energy change and AG the intrinsic barrier , the free energy of activation when AG° = 0, a constant of the particular type of reaction. [Pg.21]


See also in sourсe #XX -- [ Pg.672 ]

See also in sourсe #XX -- [ Pg.672 ]

See also in sourсe #XX -- [ Pg.676 ]




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