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10,11 -Epoxyfarnesyl acetate

SELECTIVE EPOXIDATION OF TERMINAL DOUBLE BONDS 10,11-EPOXYFARNESYL ACETATE... [Pg.112]

C. 10,11 -Epoxyfarnesyl Acetate. The bromohydrin acetate prepared in Part B is dissolved in 300 ml. of methanol, the solution is placed in a... [Pg.113]

The MesSiCl/col couple has also proved to be a suitable regenerating agent for Cp2TiCl-catalyzed cascade cyclizations of epoxypolyprenes [53]. Thus, the catalytic cyclization of epoxyfarnesyl acetate (4) (Scheme 12), for example, provided substantially increased yields of alkene 5 (40% versus the 25% obtained by the stoichiometric version) whilst employing lower titanocene proportions and dilution levels by one and two orders of magnitude, respectively. [Pg.70]

Scheme 12 Titanocene-catalyzed cyclization of epoxyfarnesyl acetate [53]... Scheme 12 Titanocene-catalyzed cyclization of epoxyfarnesyl acetate [53]...
See other pages where 10,11 -Epoxyfarnesyl acetate is mentioned: [Pg.57]    [Pg.79]    [Pg.57]    [Pg.149]   
See also in sourсe #XX -- [ Pg.56 , Pg.112 ]

See also in sourсe #XX -- [ Pg.50 ]

See also in sourсe #XX -- [ Pg.56 , Pg.112 ]



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