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Enzymes causing aldol reaction

Show the mechanism for the aldol condensation shown in the second step of the process outlined in Figure 28.1. Assume that the reaction is caused by base and ignore the effect of the enzyme. [Pg.1187]

Concerning the reaction S5rstems, hydrophobic aldehydes need cosolvents to enhance their solubility and up to 20% (v/v) dimethylformamide (DMF) or dimethylsulfoxide (DMSO) is usually tolerated by the enzyme without compromising its activity. Emulsions are alternative systems for hydrophobic acceptors, but substrate partitioning between phases may cause rate limitations, particularly for substrates with high values [96]. Examples of aldol additions catalyzed... [Pg.302]

See other pages where Enzymes causing aldol reaction is mentioned: [Pg.189]    [Pg.7]    [Pg.93]    [Pg.67]    [Pg.798]    [Pg.113]    [Pg.490]    [Pg.142]    [Pg.67]    [Pg.67]    [Pg.470]    [Pg.61]   
See also in sourсe #XX -- [ Pg.189 ]



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