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Entering group effect platinum complexes

Entering group effect platinum complexes substitution reactions, 494 EXAFS spectroscopy cadmium complexes, 929 copper(II) complexes, 720 zinc complexes, 929... [Pg.6048]

Entering Groups. Rates of reaction of [PtCl4], [PtCl3(OH2)], and [PtCl2(OH2)2] with ethene are all rather similar. Rates and activation parameters for the reaction of a variety of uncharged platinum(ii) complexes with cyanide have been reported. The complexes in question are [PtCl(N02)(NH3)2], [Pt(N02)2(NH3>2], [Pt(CN)a-(en)], and rra s -[Pt(CN)(N02)(NH3)2] cyanide substitution follows the usual rate law [equation (1) above]. The variation of the second-order term with solvent composition for the reaction of [PtCl2(bipy)] with thiourea in aqueous dioxan and in aqueous THE has been discussed in terms of solvent effects on the initial and transition states (see Chapter 5 of this Part). ... [Pg.156]

See other pages where Entering group effect platinum complexes is mentioned: [Pg.126]    [Pg.126]    [Pg.353]    [Pg.3882]    [Pg.867]    [Pg.3881]    [Pg.5226]    [Pg.459]    [Pg.142]    [Pg.622]    [Pg.145]    [Pg.151]    [Pg.5457]    [Pg.5468]    [Pg.278]    [Pg.27]    [Pg.39]    [Pg.132]    [Pg.528]    [Pg.5456]    [Pg.5467]    [Pg.330]    [Pg.144]   


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