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Enolates continued Michael reaction

The second chapter, by David A. Oare and Clayton H. Heathcock, deals with the stereochemistry of uncatalyzed Michael reactions of enamines and of Lewis acid catalyzed reactions of enol ethers with a,/ -unsaturated carbonyl compounds. It is effectively a continuation of their definitive review of base-promoted Michael addition reaction stereochemistry that appeared in the preceding volume of the series. [Pg.353]

Aldol reaction. A new catalyst for the Mukaiyama version of an aldol reaction is [Ir(cod)(PPh3)2]OTf. Actually, after activation by hydrogen, it promotes a Michael reaction of enones with silyl enol ethers and the system can be modified to continue an aldol reaction. [Pg.238]


See other pages where Enolates continued Michael reaction is mentioned: [Pg.255]    [Pg.467]    [Pg.31]    [Pg.673]    [Pg.162]    [Pg.202]    [Pg.20]    [Pg.249]    [Pg.673]    [Pg.673]    [Pg.285]    [Pg.240]    [Pg.116]    [Pg.649]   


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Continuous reactions

Enolates Michael

Enolates continued)

Michael reactions continued)

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