Enolate ion stability

The adduct formed initially is itself an enolate ion stabilized by resonance. [Pg.132]

The enolate ion leading to 2,2-dimethylcyclohexanone is the thermodynamic enolate ion because it is the more stable enolate ion since it has the more substituted double bond. (Alkyl substitution increases enolate ion stability for the same reason that it increases alkene stability Section 6.13.) Therefore, 2,2-dimethylcyclohexanone is the major product if the reaction is carried out under conditions that cause enolate ion formation to be reversible. [Pg.864]

See also in sourсe #XX -- [ Pg.2 , Pg.3 , Pg.4 , Pg.5 , Pg.6 , Pg.7 , Pg.8 , Pg.9 , Pg.10 , Pg.11 , Pg.12 , Pg.13 , Pg.14 , Pg.15 , Pg.85 ]

See also in sourсe #XX -- [ Pg.2 , Pg.3 , Pg.4 , Pg.5 , Pg.6 , Pg.7 , Pg.8 , Pg.9 , Pg.10 , Pg.11 , Pg.12 , Pg.13 , Pg.14 , Pg.15 , Pg.85 ]

See also in sourсe #XX -- [ Pg.878 ]

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