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Enolate anions, homoenolates enol ethers

Just as anions of allyl derivatives can be homoenolate equivalents (chapter 13) so anions of vinyl derivatives can be acyl anion equivalents. Vinyl (or enol) ethers can be lithiated reasonably easily, especially when there is no possibility of forming an allyl derivative, as with the simplest compound 81. The most acidic proton is the one marked and the vinyl-lithium derivative 82 reacts with electrophiles to give the enol ether of the product17 84. However, tertiary butyl lithium is needed and compounds with y-CHs usually end up as the chelated allyl-lithium 85. These vinyl-lithium compounds add directly to conjugated systems but the cuprates will do conjugate addition.18... [Pg.210]


See other pages where Enolate anions, homoenolates enol ethers is mentioned: [Pg.1169]    [Pg.841]    [Pg.163]    [Pg.47]    [Pg.841]    [Pg.56]    [Pg.555]    [Pg.697]    [Pg.61]   
See also in sourсe #XX -- [ Pg.739 ]




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Enolate anions

Enolates anion

Enolates anionic

Homoenol

Homoenolate

Homoenolates

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