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Ene reaction allylic

DNA photooxidation, 1201-2, 1203 oxidation, 1155 disihrane oxidation, 818 ene reaction allylic hydroperoxides, 673, 831-98... [Pg.1489]

C/C-connections pericyclic reactions, ene reactions, allylation of carbonyls, Grignard-type additions to carbonyl, aldol-type additions of silyl enol ethers to carbonyl, epoxide opening with cyanide, etc. [Pg.88]

It may be recognized that the bonding in the transition state may be maximized differently for each reaction For the concerted ene reaction, allylic resonance and hence the stabilization is maximized by turning the axis of the C—H bond undergoing breakage parallel to the p orbital of the double bond. ... [Pg.167]




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