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Endocyclic lone electron pairs substituents

FIGURE 1.10 The anomeric effect, (a) The n-o interaction stabilizes the a anomer. (b) The P anomer experiences unfavorable dipole-dipole interaction that is reduced in the a anomer. (c) Greater electrostatic repulsion between the lone-pair electrons of the endocyclic oxygen and the electronegative anomeric substituent in the (1 anomer. [Pg.11]


See other pages where Endocyclic lone electron pairs substituents is mentioned: [Pg.191]    [Pg.191]    [Pg.34]    [Pg.11]    [Pg.189]    [Pg.344]    [Pg.59]    [Pg.90]    [Pg.186]    [Pg.1034]    [Pg.195]    [Pg.374]    [Pg.111]    [Pg.59]   
See also in sourсe #XX -- [ Pg.191 ]




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