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Encounter complexes stability compared

Chromium(IV) and chromium(V), previously encountered as the oxides and halides and as unstable intermediates in solution, are now represented by complexes of ligands stabilized by heavy substitution against oxidation by the metal ion, and oxo and nitrido derivatives. These remain unimportant oxidation states compared with molybdenum and tungsten. [Pg.701]

This can be rationalized by noting that the sulfate head groups have some affinity for Cu(II) and may be decreasing the copper mobility through complexation. In any case the affect is not large. When HTAC or HTAB are added it is clear from the rate Increases that a mechanism which relys only on a random encounter in the Interphase is no longer applicable. Insight into the rate enhancement process can be obtained if we compare the stability for the formation of CuBr and CuCl. Log 64 for the reaction ... [Pg.170]


See other pages where Encounter complexes stability compared is mentioned: [Pg.2]    [Pg.2589]    [Pg.2107]    [Pg.778]    [Pg.200]    [Pg.170]    [Pg.76]    [Pg.193]    [Pg.50]    [Pg.68]    [Pg.191]    [Pg.299]    [Pg.30]    [Pg.189]    [Pg.185]    [Pg.828]    [Pg.22]    [Pg.1]    [Pg.982]    [Pg.816]    [Pg.7]    [Pg.426]    [Pg.60]    [Pg.577]    [Pg.140]    [Pg.666]    [Pg.429]    [Pg.1463]    [Pg.20]    [Pg.910]    [Pg.263]    [Pg.577]    [Pg.313]    [Pg.106]   
See also in sourсe #XX -- [ Pg.259 ]




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