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Enantioselectivity ring-opening polymerization

Lipase catalysis is often used for enantioselective production of chiral compounds. Lipase induced the enantioselective ring-opening polymerization of racemic lactones. In the lipase-catalyzed polymerization of racemic (3-BL, the enantioselec-tivity was low an enantioselective polymerization of (3-BL occurred by using thermophilic lipase to give (/ )-enriched PHB with 20-37% enantiomeric excess (ee). ... [Pg.219]

Al-Azemi TF, Kondaveti L, Bisht KS (2002) Solventless enantioselective ring-opening polymerization of substituted-caprolactones by enzymatic catalysis. Macromolecules 35 3380-3386... [Pg.216]

Enantioselective Ring-Opening Polymerizations of Substituted Lactones Using Lipases... [Pg.101]

Ligand Design in Enantioselective Ring-opening Polymerization of Lactide... [Pg.270]

Scheme 11.9 Enantioselective ring opening polymerization of methyl substituted 4-membered resulting in the formation of enantiomerically enriched (a) poly(S-2-methylpropionate) (S-30) and (b) poly(R-3-hydroxybutyrate) (R-32). Scheme 11.9 Enantioselective ring opening polymerization of methyl substituted 4-membered resulting in the formation of enantiomerically enriched (a) poly(S-2-methylpropionate) (S-30) and (b) poly(R-3-hydroxybutyrate) (R-32).
See other pages where Enantioselectivity ring-opening polymerization is mentioned: [Pg.80]    [Pg.453]    [Pg.70]    [Pg.87]    [Pg.95]    [Pg.112]    [Pg.95]    [Pg.112]   


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Enantioselective polymerization

Enantioselective ring-opening

Ligand Design in Enantioselective Ring-opening Polymerization of Lactide

Ring enantioselective

Ring-opening polymerization enantioselective

Ring-opening polymerization enantioselective

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