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Enantioselectivity photoredox organocatalysis

Nagib DA, Scott ME, MacMillan DWC (2009) Enantioselective a-trifluoromethylation of aldehydes via photoredox organocatalysis. J Am Chem Soc 131 10875-10877... [Pg.102]

Scheme 15.107 Enantioselective trifluoromethylation of aldehydes mediated by coupled photoredox/organocatalysis. Scheme 15.107 Enantioselective trifluoromethylation of aldehydes mediated by coupled photoredox/organocatalysis.
The merging of photoredox catalysis with asymmetric organocatalysis was reported by MacMillan and Nicewicz in 2008 [104]. Initial studies in the MacMillan group were devoted to the imidazolidinone-catalyzed asymmetric a-functionaliza-tion of aldehydes with a-bromo ketones and esters [104a] and were subsequently expanded to enantioselective perfluoroalkylations [105] and benzylations [106]. The... [Pg.45]

Hong BC, Lin CW, Liao WK, Lee GH (2013) Sequential asymmetric catalysis in Michael-Michael-Michael aldol reactions merging organocatalysis with photoredox catalysis in a one-pot enantioselective synthesis of highly functionalized decalines bearing a quaternary carbon stereocenter. Org Lett 15 6258-6261... [Pg.226]

See other pages where Enantioselectivity photoredox organocatalysis is mentioned: [Pg.6]    [Pg.159]    [Pg.1180]    [Pg.365]    [Pg.1180]   


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Enantioselective Organocatalysis

Enantioselectivity organocatalysis

Organocatalysis

Photoredox organocatalysis

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