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Enantioselective synthesis of solenopsin

At atmospheric pressure, the conversion of sterically hindered primary and secondary alcohols into the corresponding phenyl sulfide derivatives with a BusP-PhSSPh system occurs in low yields (0-56%) at 1.0 GPa pressure, the same reactions have given a 65-100% yield.Thus, this reaction has been used in the seven-step enantioselective synthesis of (-)-solenopsin... [Pg.253]

See also in sourсe #XX -- [ Pg.6 , Pg.429 , Pg.430 ]

See also in sourсe #XX -- [ Pg.6 , Pg.429 , Pg.430 ]



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Solenopsin

Solenopsin synthesis

Solenopsine

Solenopsins, synthesis

Synthesis enantioselective

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