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Enantioenriched cyclopropylmethanols

The dioxaborolane ligand 1 has been found to effectively convert allylic alcohols to their corresponding enantioenriched cyclopropylmethanols in high yields and high enantiomeric excesses. The Zn(CH2l)2 reagent or its DME... [Pg.137]

Figure 1 Representative examples of enantioenriched cyclopropylmethanols obtained from allylic alcohols using the dioxaborolane ligand 1 and bis(iodomethyl)zinc. Figure 1 Representative examples of enantioenriched cyclopropylmethanols obtained from allylic alcohols using the dioxaborolane ligand 1 and bis(iodomethyl)zinc.


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Cyclopropylmethanols

Enantioenrichment

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