Elution Order and Absolute Configuration

The results for the DEAE-cellulose—HCl system (Table 3.6 show that for the 

The resolution by the mentioned column chromatography for chiral complexes is based on the interaction between a chiral adsorbent and a chiral eluent. From such a point of view the association constants have been determined for the ion pairs. A- and A-[Co(en)3p with L(+)-tartrate dianion and with L(-i-)-tartratoanti-monate(III) dianion ((+)-tartan), on the basis of CD measurements at two wave- 

Taide 3.5. Correlation between Sign CD Peak of the First Eluted Enantiomers and Thdr Absolute Configuration 

Isomer Sign of the longer wavelength CD peak Absolute configuration 

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