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Elimination of Allylpalladium and Related Derivatives

V.2.5.1 ELIMINATION OF ALLYLPALLADIUM AND RELATED DERIVATIVES 1985 TABLE 2. Elimination Reactions of Geranyl Acetate, Neryl Acetate, and Linalyl Acetate... [Pg.347]

As a related reaction, Yamamoto reported a novel allylative dearomatization to give 6-allyl-3-mettiylene-l,4-cyclohexadiene (373) by the reaction of benzyl chloride and allylstaimane under mild conditions. In this reaction, the 7r-benzylpalla-dium species 370 is generated from benzylpalladium 369. The bis-7r-allylpalladium species 371 and 372 are generated by the reaction of tt-benzylpalladium 370 with allylstaimane. Finally the dearomatization product 373 is formed from 372 by reductive elimination. It is surprising that the dearomatization product 373 is rather stable and no isomerization to a benzene derivative was observed at room temperature [142]. [Pg.479]

See other pages where Elimination of Allylpalladium and Related Derivatives is mentioned: [Pg.343]    [Pg.345]    [Pg.349]    [Pg.353]    [Pg.355]    [Pg.343]    [Pg.345]    [Pg.349]    [Pg.353]    [Pg.355]    [Pg.36]    [Pg.362]    [Pg.188]    [Pg.1686]    [Pg.20]    [Pg.1687]    [Pg.468]   


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Allylpalladium

Related Derivatives

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