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Electros triction

Reaction and activation volumes are in general considered to consist of solvational and intrinsic contributions that arise from changes in electros-triction and changes in bond lengths and angles during the chemical process, respectively. It follows from the above given relationships that a volume... [Pg.63]

In the case of electron-transfer reactions, significant changes in electros-triction are expected to affect the values of AV and AV, such that the... [Pg.64]




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