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Transition-metal dichalcogenides electronic structure

The class of layered transition metal dichalcogenides has been of great interest because of their varied electronic properties and chemical reactions. Most compounds of this class may be prepared by stoichiometric reactions of the elements above 500°. However, the highest vanadium sulfide that can be made in this manner is VjSg. An amorphous VS has been prepared by the metathetical reaction of LijS and VC. The method presented here allows preparation of polycrystalline VSj with the Cdiz structure. ... [Pg.201]

Fig. 1. Schematic representation of structure, crystal symmetry and energetic distribution of electronic d-states derived from the transition metal (M-d) in semiconducting dichalcogenides of Group TV, VI and VIII and semimetallic compounds of Group V... Fig. 1. Schematic representation of structure, crystal symmetry and energetic distribution of electronic d-states derived from the transition metal (M-d) in semiconducting dichalcogenides of Group TV, VI and VIII and semimetallic compounds of Group V...

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See also in sourсe #XX -- [ Pg.96 , Pg.97 , Pg.98 ]




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