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Electronic Properties of Free and Coordinated Silyl Groups

Electronic Properties of Free and Coordinated Silyl Groups [Pg.197]

CHAPTER 4 COVALENT (x-TYPe) LIGANDS BOUND THROUGH METAL-HETEROATOM BONDS [Pg.198]

Back-donation from L M into the Si-R r -orbital (not into the Si d-orbital) [Pg.198]

Often shorter than the -sum of van der Waals radii for late metals M [Pg.198]

Weaker donor than an alkyl based on Hammett parameters [Pg.198]

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Coordinates electron

Coordinating groups

Coordination Group

Coordination properties

Electronic coordinate

Free electrons

Property group

Silyl groups