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Electronic equilibria, paramagnetic species

The mercurous ion is the only common ionic species having a metal-to-fnetal bond. There are a number of ways of demonstrating that univalent mercury is indeed dimeric the presence of mercury-to-mercury bonds has been revealed by x-ray studies of crystalline mercury(I) chloride and also by spectral studies of aqueous mercury(I) nitrate, whereas magnetic studies of solutions containing univalent mercury show none of the paramagnetism that would be expected if such solutions were to contain Hg+ ions (with an odd number of electrons per ion). Aside from this evidence, a number of studies of equilibrium relations in systems containing the mercurous ion show that the ion is Hg Hg2+ rather than Hg+ (Exercise 5). [Pg.200]

See other pages where Electronic equilibria, paramagnetic species is mentioned: [Pg.1564]    [Pg.849]    [Pg.237]    [Pg.235]    [Pg.366]    [Pg.345]    [Pg.243]    [Pg.72]    [Pg.1564]    [Pg.378]    [Pg.414]    [Pg.311]    [Pg.304]    [Pg.53]    [Pg.415]    [Pg.1357]    [Pg.39]    [Pg.492]    [Pg.28]    [Pg.127]    [Pg.736]    [Pg.943]    [Pg.115]    [Pg.38]    [Pg.2043]    [Pg.3951]    [Pg.6311]    [Pg.437]    [Pg.586]    [Pg.95]    [Pg.69]    [Pg.586]    [Pg.130]    [Pg.357]    [Pg.158]    [Pg.158]    [Pg.898]    [Pg.437]    [Pg.69]    [Pg.2042]    [Pg.3950]    [Pg.6310]    [Pg.237]    [Pg.174]    [Pg.736]    [Pg.943]    [Pg.3196]    [Pg.4397]    [Pg.1348]    [Pg.1030]   
See also in sourсe #XX -- [ Pg.54 , Pg.55 ]



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16-electron species

Electron paramagnetic

Equilibria species

Paramagnetic species

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