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Electronic configuration pair reversals

The orbitals of like symmetry interact, the lower being stabilized at the expense of the upper. The resulting through-bond interaction [24] reverses their order, so that the electronic configuration of the trans-stable radical becomes [a 6 ] like that of the reactant pair of ethylenes. [Pg.145]

As a result of the presence of lone-pair electrons, the configuration of orga-nosulfur species is pyramidal, and the pyramidal reversion is normally slow at ambient temperature. Thus two enantiomers of chiral sulfoxides are possible and separable. [Pg.9]

See other pages where Electronic configuration pair reversals is mentioned: [Pg.79]    [Pg.10]    [Pg.376]    [Pg.231]    [Pg.211]    [Pg.27]    [Pg.663]    [Pg.268]    [Pg.292]    [Pg.341]    [Pg.268]    [Pg.347]    [Pg.242]    [Pg.76]    [Pg.206]    [Pg.304]    [Pg.848]    [Pg.1006]    [Pg.1452]    [Pg.136]    [Pg.218]    [Pg.256]    [Pg.171]    [Pg.553]    [Pg.199]    [Pg.603]    [Pg.119]    [Pg.165]    [Pg.740]    [Pg.382]    [Pg.102]    [Pg.522]    [Pg.107]    [Pg.775]    [Pg.130]    [Pg.72]    [Pg.407]    [Pg.569]    [Pg.194]    [Pg.593]    [Pg.127]    [Pg.18]    [Pg.1452]    [Pg.29]    [Pg.240]    [Pg.47]    [Pg.320]    [Pg.400]   
See also in sourсe #XX -- [ Pg.96 , Pg.103 , Pg.131 ]



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Electron reversibility

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