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Electronic bite angle effect

They constitute the first rhodium phosphine modified catalysts for such a selective linear hydroformylation of internal alkenes. The extraordinary high activity of 32 even places it among the most active diphosphines known. Since large steric differences in the catalyst complexes of these two ligands are not anticipated, the higher activity of 32 compared to 31 might be ascribed to very subtle bite angle effects or electronic characteristics of the phosphorus heterocycles. [Pg.160]

Bite angle effects in diphosphine metal catalysts Steric or electronic ... [Pg.297]

Freixa, Z. and van Leeuwen, P.W.N.M. (2003) Bite angle effects in diphosphine metal catalysts Steric or electronic Dalton Trans., 1890. [Pg.122]

See other pages where Electronic bite angle effect is mentioned: [Pg.19]    [Pg.76]    [Pg.1]    [Pg.2]    [Pg.5]    [Pg.7]    [Pg.12]    [Pg.19]    [Pg.76]    [Pg.1]    [Pg.2]    [Pg.5]    [Pg.7]    [Pg.12]    [Pg.235]    [Pg.254]    [Pg.311]    [Pg.3]    [Pg.21]    [Pg.242]    [Pg.327]    [Pg.187]    [Pg.755]    [Pg.157]    [Pg.157]    [Pg.203]    [Pg.387]    [Pg.163]    [Pg.163]    [Pg.181]    [Pg.162]    [Pg.18]    [Pg.40]    [Pg.159]    [Pg.291]    [Pg.72]    [Pg.3]    [Pg.250]    [Pg.161]    [Pg.457]    [Pg.441]    [Pg.443]    [Pg.456]    [Pg.21]    [Pg.333]    [Pg.122]    [Pg.155]    [Pg.141]    [Pg.29]   
See also in sourсe #XX -- [ Pg.19 ]

See also in sourсe #XX -- [ Pg.5 ]



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