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Mulliken-Jaffd electronegativities

Muetterties, E. L., 223, 241 Mflller, K. A., 285 Mulliken-Jaffd electronegativities, 183-186, 258 Mulliken labels, 61 Multiplicity. 26-27 Myoglobin... [Pg.536]

This is the simplest expression for charge (ionicity) in the Mulliken-Jaffd system with electronegativity equalization (see Eq. 5.85). The boundary lines in Fig. 7.6 radiate more or less from the origin with the slope of m from Eq. 7.1. We may thus infer that each represents a line of constant ionicity that is responsible for the changeover from one structure type to the next. [Pg.141]

Recently Parr and Pearson have used the b parameter to investigate the hard and soft properties of metal ions and ligands. They have termed this the absoliiie hardness in comparison to the Mulliken-Jaffd a parameter which they call absolute electronegativity. They provide strong arguments for the use of the absolute hardness parameter in treating hard-soft acid-base (HSAB) interactions. [Pg.351]


See other pages where Mulliken-Jaffd electronegativities is mentioned: [Pg.641]    [Pg.641]    [Pg.629]    [Pg.632]    [Pg.634]    [Pg.185]    [Pg.195]    [Pg.195]    [Pg.341]    [Pg.195]    [Pg.195]    [Pg.341]   


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Mulliken

Mulliken electronegativity

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