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Electron-rich analogues

The archetype of the arylpentazoles, the only pentazoles of proven structurre thus far isolated, it is liable to explode above —5°C. Larger and more electron rich analogues are more stable, but still explosive. [Pg.825]

Scheme 6 Electron-rich analogues of olefin metathesis active complexes... Scheme 6 Electron-rich analogues of olefin metathesis active complexes...
Alkynylation. Addition of 1-alkynes to a-keto esters is catalyzed by (acac)Rh(CO)2 in the presence of a hindered phosphine ligand [e.g., 2-(di-t-butylphosphino)biphenyl]. Complexes containing more electron-rich analogues of the acetylaetonato ligand favor the reaction. [Pg.1]

Indole is a heterocycHc analogue of naphthalene. The basic reactivity patterns of indole can be understood as resulting from the fusion of an electron-rich pyrrole ring with a ben2ene ring. [Pg.84]

The dipole moment varies according to the solvent it is ca 5.14 x 10 ° Cm (ca 1.55 D) when pure and ca 6.0 x 10 ° Cm (ca 1.8 D) in a nonpolar solvent, such as benzene or cyclohexane (14,15). In solvents to which it can hydrogen bond, the dipole moment may be much higher. The dipole is directed toward the ring from a positive nitrogen atom, whereas the saturated nonaromatic analogue pyrroHdine [123-75-1] has a dipole moment of 5.24 X 10 ° C-m (1.57 D) and is oppositely directed. Pyrrole and its alkyl derivatives are TT-electron rich and form colored charge-transfer complexes with acceptor molecules, eg, iodine and tetracyanoethylene (16). [Pg.354]

Paradoxically, although they are electron-rich, S-N compounds are good electron acceptors because the lowest unoccupied molecular orbitals (LUMOs) are low-lying relative to those in the analogous carbon systems. For example, the ten r-electron [SsNs] anion undergoes a two-electron electrochemical reduction to form the trianion [SsNs] whereas benzene, the aromatic hydrocarbon analogue of [SsNs], forms the monoanion radical [CeHg] upon reduction. ... [Pg.43]

This technique has also been applied in the synthesis of carbostyril analogues 15 and as in the previous example also this reaction is favored by an electron-rich group in the aniline-ring and an electron-poor group attached to the electrophihc specie (b. Scheme 6) [55]. The use of microwave irradiation can reduce the reaction times from 18-58 h to 80 min and the products are generally isolated in high yields and purities. [Pg.319]

The Diels-Alder cycloaddition potential of fused 4-aryldihydropyrimidine mesomeric betaines has been studied. The cross-conjugated thiazinium betaine 317 underwent 1,4-dipolar cycloaddition with electron-rich dipolaro-philes, and thus 1-diethylaminoprop-l-ine gave the pyrido[l,2-tf]pyrimidine 318 by loss of carbonyl sulfide (Equation 34). Reaction of 317b with 1,1-diethoxyethene resulted in the 8-ethoxy analogue of 318 (R = H) <1997JOC3109>. [Pg.302]

Nitrogen substituted porphyrazines were the second type of heteroatom-deriva-tized pz macrocycle reported and were prepared from the readily derivatized diami-nomalconitrilc (DAMN) (7). Octakis(dimethylamino)porphyrazines are extremely electron-rich systems and have been used to prepare charge-transfer complexes with Cgo, as well as to peripherally chelate metals or convert to crown appended systems (38, 39). The unsymmetrical dimethylaminoporphyrazine analogues have also been reported (29), as well as the first example of the desymmetrized seco-pz from the dimethylaminoporphyrazine (8, 40). The nitrogen substituted porphyrazines are discussed in Section V. [Pg.479]

In addition to these extensive studies on electrophile-mediated intramolecular peroxydation of electron-rich C=C bonds, some examples of intramolecular hydroperoxide addition to electron-poor C=C bonds have been described. For example, several racemic analogues 371 of the naturally occurring plakinic acid were readily obtained by peroxymercuration followed by hydridodemercuration of the dienic acids 370 (Scheme 95 f °. Intramolecular Michael addition of hydroperoxide function to the double... [Pg.242]


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Electron richness

Electron-rich

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