Electron paramagnetic resonance rotational diffusion

Thomas, D.D., Dalton, L.R., and Hyde, J.S. 1976. Rotational diffusion studied by passage saturation transfer electron paramagnetic resonance. The Journal of Chemical Physics 65 3006-3024. [Pg.238]

Budil DE, Earle KA, Freed JH (1993) Full determination of the rotational diffusion tensor by electron-paramagnetic resonance at 250 GHz. J Phys Chem 97 1294—1303... [Pg.113]

AcAc, acetylacetonate EPR, electron paramagnetic resonance DPM, dipivaloylmethane Tc, Correlation time for molecular tumbling A/x, concentration of spins X (per unit volume) D, mutual translational self-diffusion coefficient of the molecules containing A and X a, distance of closest approach of A and X ye, magnetogyric ratio for the electron C, spin-rotation interaction constant (assumed to be isotropic) Ashielding anisotropy <7 <7j ) coo, Debye frequency 0d, the corresponding Debye temperature Fa, spin-phonon coupling constant. [Pg.3261]