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Electron diffraction, allyl radical

The allyl radical would be expected to be planar in order to maximize n delocalization. Molecular structure parameters have been obtained from EPR, IR, and electron diffraction measurements and confirm that the radical is planar. ... [Pg.679]

Later, successful determination of the molecular structure of the free allyl radical was achieved by high-temperature electron diffraction, augmented by mass spectrometry studies (Vaida et al., 1986). The structural parameters obtained for the allyl radical were rcc 142.8 pm, rcH 106.9 pm, accc 124.6°, ccH 120.9°. This was the first electron diffraction study of an unstable organic molecule. [Pg.39]


See other pages where Electron diffraction, allyl radical is mentioned: [Pg.38]    [Pg.38]    [Pg.266]    [Pg.189]    [Pg.270]    [Pg.985]    [Pg.189]    [Pg.274]    [Pg.311]    [Pg.725]   
See also in sourсe #XX -- [ Pg.270 ]




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Electron diffraction

Electron diffraction, allyl

Electron radicals

Electronic diffraction

Electrons diffracted

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Radicals) allylations

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