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Electron-deficient bridge-bonded main bonding

The purpose of this review is to summarize the recent information available on the structures of derivatives of the main group elements that contain electron-deficient bridge bonds and to focus attention on the relationships between the structures and the bonding in these molecules. [Pg.236]

J. P. Oliver, Structures of main group organometallic compounds containing electron-deficient bridge bonds. Adv. Organomet. Chem. 15, 235-271 (1977). [Pg.451]

Structures of Main Group Organometallic Compounds Containing Electron-Deficient Bridge Bonds, 15, 235... [Pg.324]

According to theoretical studies, the HOMO of benzocyclopropene is mainly located at the bridging rr-bond and it therefore would be predicted that it would participate in cycloadditions with electron-deficient dienes. Stable adducts 1 with the norcaradiene structure were obtained upon heating benzocyclopropene with 4,5-dibromo-l,2-benzoquinone, 4,5-dichloro-l,2-ben-zoquinone and tetrachlorobenzoquinone. ... [Pg.2919]


See other pages where Electron-deficient bridge-bonded main bonding is mentioned: [Pg.511]    [Pg.326]    [Pg.318]    [Pg.470]    [Pg.362]    [Pg.239]    [Pg.268]    [Pg.85]    [Pg.86]    [Pg.236]    [Pg.7]    [Pg.129]    [Pg.589]    [Pg.700]    [Pg.417]    [Pg.560]    [Pg.313]    [Pg.417]    [Pg.614]    [Pg.416]    [Pg.261]    [Pg.974]    [Pg.353]    [Pg.19]    [Pg.63]   
See also in sourсe #XX -- [ Pg.236 , Pg.237 , Pg.238 , Pg.249 , Pg.260 , Pg.261 ]




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Bonding bridge (‘electron-deficient

Bridge bond

Bridge-bonding

Bridging 2-bond 2-electron

Electron deficiency

Electron-deficient bond

Electron-deficient bonding

Main bridge

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