Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Electromagnetic transition amplitudes

In fig. la-c the distribution function (14) is compared for isoscalar Ml-, E2- and E4-electromagnetic transition amplitudes with shell-model results for 20Ne(T s0,T2 0), calculated in the sd-conf iguration space. A surface delta interaction was used with strength parameters [BRU77] Aq Aj ... [Pg.125]

When a(f) = 1, the field E t) in Eq. (7.24) describes a continuous wave with amplitude Eq. The transition probability to the excited state is given by (X2(t) x2(t), and in this case a constant transition probability per unit time is found (after a few oscillations of the electromagnetic field). For a direct reaction, this is equal to the rate constant of Eq. (7.5), kn(hv). Using Eq. (7.28), it is found [3,4] that... [Pg.182]

Thus, probing the response from root state k with electromagnetic (EM) radiation matching the gap (ek - ek/) actually would elicit the amplitude at state k ). The root state is also defined as the initial state for a transition k -> k ... [Pg.52]

NMR arises from transitions between energy levels, just as in other branches of spectroscopy, with transitions induced by the absorption of energy from an applied electromagnetic field with a magnetic amplitude of 2B,.The interaction... [Pg.18]

From Equation (1.35), the electric dipole transition moment Afo f may be thought of as the dipole moment of the transition density The transition density is a purely quantum mechanical quantity and cannot be inferred from classical arguments. A more pictorial representation of the electric dipole transition moment equates it to the amplitude of the oscillating dipole moment of the molecule in the transient nonstationary state that results from the mixing of the initial and the final states of the transition by the time-dependent perturbation due to the electromagnetic field, and which can be written as a linear combination Cq o + + This emphasizes the fact... [Pg.25]

This relation contains the wavefunction for first-order perturbation i//g1 (r, t), describing the interaction of light with matter at low intensities, the excitation frequency (transition frequency from the ground state to the final excited state (a fg), the amplitude of the electromagnetic wave C40), the electronic charge... [Pg.118]

When the photons are linearly polarized, the Rabi frequencies = ( d p)/27i coincide with the above defined Rabi frequencies. We assume real transition dipole moments and amplitudes of the electromagnetic fields and use the following expressions for the field amplitudes, = fit/cen. = Jlle/ceQ. Here = e , > = e> e and e are the polarization vectors of strong pump and ASE fields. [Pg.225]

When an electronic transition of a thermally equilibrated molecule is excited by a short pulse of electromagnetic radiation at t = 0, amplitude is removed from rotational-vibrational states of the electronic ground state, g, and amplitude is created in rotational-vibrational states of an electronically excited state, e. At t < 0, the molecular density matrix is entirely diagonal and time-independent,... [Pg.639]

To begin with, consider the simplest and best known gauge theory— QED. As a result of the gauge invariance there are equations of constraint (the Ward-Takahashi identities mentioned in Section 1.1) that must be satisfied by certain matrix elements. For example, because the photon is coupled to the electromagnetic current in the form J, the amplitude for a photon to cause a transition from some state a) to /3) as shown,... [Pg.170]


See other pages where Electromagnetic transition amplitudes is mentioned: [Pg.122]    [Pg.123]    [Pg.124]    [Pg.126]    [Pg.122]    [Pg.123]    [Pg.124]    [Pg.126]    [Pg.103]    [Pg.127]    [Pg.129]    [Pg.2458]    [Pg.31]    [Pg.65]    [Pg.289]    [Pg.318]    [Pg.303]    [Pg.276]    [Pg.147]    [Pg.256]    [Pg.273]    [Pg.169]    [Pg.256]    [Pg.76]    [Pg.349]    [Pg.124]    [Pg.124]    [Pg.401]    [Pg.520]    [Pg.118]    [Pg.635]    [Pg.9]    [Pg.2458]    [Pg.111]    [Pg.303]    [Pg.480]    [Pg.332]    [Pg.36]    [Pg.64]    [Pg.1799]    [Pg.18]    [Pg.2099]    [Pg.36]   


SEARCH



Electromagnetic transition

Electromagnetic transition amplitudes distribution

Transition amplitudes

© 2024 chempedia.info