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Electrolytic cleavage tosylate

Electrolysis, Me4N Cl , 5°, 65-98% yield. " Acylation of a tosylated amine with BOC or benzoyl reduces the potential required for electrolytic cleavage so that these aryltosyl groups can be selectively removed in the presence of a simple tosylamide. °... [Pg.605]

Electrolysis of a tosylate in methanol as electrolyte recovers the alcohol with retention of configuration by cleavage of the 0-S02 bond 514 In aprotic solvents (CH3CN) this cleavage is not so clean, alcohol, ether and toluene being formed simultaneously 515 Electrolysis of diaryl and arylalkylsulfones forms... [Pg.137]

Tosyl sulphonamides /R1 TosN XR2 Products of cleavage in tetramethylammonium salt as an electrolyte ... [Pg.564]


See other pages where Electrolytic cleavage tosylate is mentioned: [Pg.171]    [Pg.395]    [Pg.21]   
See also in sourсe #XX -- [ Pg.432 ]




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Electrolytic cleavage, 3

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